Developers highlight the benefits of conversational LLM-based “programming assistants”. However, recent studies demonstrate the variety in individual developers’ needs regarding programming assistants, and challenges encountered by only specific groups of developers. In this study, we explore the role of cognitive diversity in shaping interactions with GitHub Copilot chat. Through a mixed-methods think aloud study with 27 professional developers and students, we characterize 5 distinct “interaction modes” and 10 underlying needs in developers’ interactions, forming a conceptual model. We characterize links between these modes, needs, and developers’ problem-solving styles and experience profiles, showing how cognitive diversity may shape developers’ interactions. We provide insights and recommendations for researchers and practitioners on how to design programming assistants to better account for diverse developer needs.